Early Morning is considered as the best time to worship God. Early morning is also known as "Brahma Mahurat" in the Hindu Mythology. It is regarded that prayers made at this time reach directly to the God. Early Morning Shloka (Sloka) is given here which also serves as the first prayer of the day to the almighty.
Karaagre Vasate Lakshmi Karamadhye  Sarasvati,
  Karamuule Tu Govinda Prabhaate Karadarshanam, 
  Samudravasane Devi Parvatastanamandale, 
  Vishhnupatni Namastubhyam Paadasparsham Kshamasva Me
Meaning: The front part of  the hands (the finger tips) is credited to Goddess Lakshmi, the Goddess of  wealth. The middle part or palm is credited to Goddess Saraswati, the Goddess  of learning and the root (the part of hand near the wrist) to Govinda. So,  every morning, one should have a reverent look at one's hand which represents  sincere labor.
  
  I bow to Mother Earth, who has mountains and jungles on her body and whose  clothing is made by the ocean. The wife of Lord Vishnu, please pardon me for  touching you with my feet. 
  
  It is considered propitious to start the day with this sincere prayer.
 

 
